I am a python developer and I would always choose python over php in any application, Emotu Balogun of http://traclist.com is also a python developer, Seun Osewa of http://nairaland.com is an amazing python proponent too. There are also a lot of people who use Python in their quest to study artificial intelligence / machine learning.
Python is now included in the Computer Science curriculum in some Nigerian universities including FUTA.
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